The creation of millimeter wave, 3D-printable dielectric nanocomposite is demonstrated. Alumina nanoparticles were combined with styrenic block copolymers and solvent to create shear thinning, viscoelastic inks that are printable at room temperature. Particle loadings of up to 41 vol % were achieved. Upon being dried, the highest-performing of these materials has a permittivity of 4.61 and a loss tangent of 0.00298 in the K band (26.5-40 GHz), a combination not previously demonstrated for 3D printing. These nanocomposite materials were used to print a simple resonator device with predictable pass-band features.
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http://dx.doi.org/10.1021/acsami.6b11643 | DOI Listing |
Adv Mater
January 2025
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore.
Nanophotonics
March 2024
Department of Applied Physics, Kyung Hee University, Yongin-si, Gyeonggi-do 17104, Republic of Korea.
Soft Matter
June 2023
College of Materials Science and Engineering, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Laboratory for Biopolymers and Safety Evaluation, Shenzhen University, Shenzhen 518055, P. R. China.
Pickering emulgels stabilized by graphene oxide (GO) with didodecyldimethylammonium bromide (DDAB) as an auxiliary surfactant and liquid paraffin as the oil phase have proved to be an excellent 3D printable ink. This paper elucidates the structure of such emulgels by a combination of microscopy before and after intensive shear as well as broadband dielectric spectroscopy and rheology in the linear and nonlinear regime. An increase of the DDAB surfactant and GO-contents leads to a systematic increase of modulus and viscosity, a reduction of the limits of the nonlinear regime and a more complicated variation of the normal forces, with negative normal forces at high shear rate for low GO-contents and positive normal forces at high GO-contents.
View Article and Find Full Text PDFPolymers (Basel)
May 2023
National Institute of Materials Physics, Atomistilor Street 405A, P.O. Box MG-7, 077125 Bucharest, Romania.
The purpose of this work was to obtain an elastic composite material from polymer powders (polyurethane and polypropylene) with the addition of BaTiO until 35% with tailored dielectric and piezoelectric features. The filament extruded from the composite material was very elastic but had good features to be used for 3D printing applications. It was technically demonstrated that the 3D thermal deposition of composite filament with 35% BaTiO was a convenient process for achieving tailored architectures to be used as devices with functionality as piezoelectric sensors.
View Article and Find Full Text PDFLangmuir
January 2023
MIT Lincoln Laboratory, 244 Wood Street, Lexington, Massachusetts02421, United States.
3D printed nanocomposites provide a method for generating high-performance radio frequency devices. Limited work has been done to investigate the influence the nanoparticle diameter has on the performance of 3D printable nanocomposites. We describe here the development of a family of 3D printable nanocomposite inks formulated from nanoparticles with diameters ranging from 30 to 300 nm.
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