In the title hydrate, CHNO·HO, the central 1,3-diazinan-5-ol ring adopts a chair conformation with the two benzyl substituents equatorial and the lone pairs of the N atoms axial. The dihedral angle between the aromatic rings is 19.68 (38)°. There are two intra-molecular O-H⋯N hydrogen bonds, each generating an (6) ring motif. In the crystal, classical O-H⋯O hydrogen bonds connect the 1,3-diazinane and water mol-ecules into columns extending along the axis. The crystal structure was refined as a two-component twin with a fractional contribution to the minor domain of 0.0922 (18).
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120723 | PMC |
http://dx.doi.org/10.1107/S2056989016013645 | DOI Listing |
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