AI Article Synopsis
- The compound CHNO was created through a Perkin reaction involving 2-methyl-8-hydroxyquinoline and 4-formyl-2-methylbenzoate in acetic anhydride under nitrogen.
- The molecular conformation features a 29.22° inclination between the quinoline and benzene rings, along with an intramolecular O-H⋯N hydrogen bond present in the quinoline structure.
- In the crystal, molecules form pairs of inversion dimers linked by O-H⋯O hydrogen bonds, which are further connected by C-H⋯O hydrogen bonds and C-H⋯π interactions, resulting in sheets parallel to the (10-1) plane.
Article Abstract
The title compound, CHNO, was synthesized by a Perkin reaction of 2-methyl-8-hy-droxy-quinoline and 4-formyl-2-methyl-benzoate in acetic anhydride under a nitro-gen atmosphere. The mol-ecule has an conformation about the C=C bond, and the quinoline ring system and the benzene ring are inclined to one another by 29.22 (7)°. There is an intra-molecular O-H⋯N hydrogen bond in the 8-hy-droxy-quinoline moiety. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds, forming inversion dimers with an (28) ring motif. The dimers are linked by C-H⋯O hydrogen bonds and C-H⋯π inter-actions, forming sheets parallel to plane (10-1).
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120699 | PMC |
| http://dx.doi.org/10.1107/S205698901601210X | DOI Listing |
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