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Pincer-plus-one ligands in self-assembly with palladium(ii): a molecular square and a molecular tetrahedron. | LitMetric

AI Article Synopsis

  • * The researchers discovered that under various conditions, this combination produced a molecular square and a tetrahedron.
  • * The resulting structures feature palladium(ii) centers that are coordinated with the oxidized forms of the ligand, showcasing the potential for creating complex molecular architectures.

Article Abstract

The combination of a palladium(ii) precursor with a diimine-phenol ligand and an oxidant (HO or O) under different conditions has, serendipitously, given both a molecular square and a molecular tetrahedron by self-assembly of building blocks comprising palladium(ii) centres coordinated to the oxidised forms of the ligand.

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Source
http://dx.doi.org/10.1039/c6dt04264cDOI Listing

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