We report magnetic-field-driven on-demand manipulation of liquid metal in microfluidic channels filled with base or acid. The liquid metal was coated with iron (Fe) particles and treated with hydrochloric acid to have strong bonding strength with the Fe particles. The magnetic liquid metal slug inserted in the microchannel is manipulated, merged, and separated. In addition, corresponding to the repositioning of an external magnet, the liquid metal slug can be readily moved in microfluidic channels with different angles (>90°) and cross-linked channels in any direction. We demonstrated the functionality of the liquid metal in the microfluidic channel for electrical switching applications by manipulation of the liquid metal, resulting in the sequential turning on of light emitting diodes (LEDs).
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http://dx.doi.org/10.1039/c6lc01255h | DOI Listing |
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January 2025
Beijing Advanced Innovation Center for Intelligent Robots and Systems, School of Medical Technology, Beijing Institute of Technology, Beijing, 100081, P. R. China.
The propensity of zinc (Zn) to form irregular electrodeposits at liquid-solid interfaces emerges as a fundamental barrier to high-energy, rechargeable batteries that use zinc anodes. So far, tremendous efforts are devoted to tailoring interfaces, while atomic-scale reaction mechanisms and the related nanoscale strain at the electrochemical interface receive less attention. Here, the underlying atomic-scale reaction mechanisms and the associated nanoscale strain at the electrochemical alloy interface are investigate, using gold-zinc alloy protective layer as a model system.
View Article and Find Full Text PDFChem Soc Rev
January 2025
School of materials science and engineering, Smart sensing interdisciplinary science center, Nankai university, Tianjin 300350, P. R. China.
The inspirations from nature always enlighten us to develop advanced science and technology. To survive in complicated and harsh environments, plants and animals have evolved remarkable capabilities to control fluid transfer sophisticated designs such as wettability contrast, oriented micro-/nano-structures, and geometry gradients. Based on the bioinspired structures, the on-surface fluid manipulation exhibits spontaneous, continuous, smart, and integrated performances, which can promote the applications in the fields of heat transfer, microfluidics, heterogeneous catalysis, water harvesting, Although fluid manipulating interfaces (FMIs) have provided plenty of ideas to optimize the current systems, a comprehensive review of history, classification, fabrication, and integration focusing on their interfacial chemistry and asymmetric structure is highly required.
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January 2025
Jiangsu Key Laboratory of Biofunctional Materials, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China.
Xylene isomers, including -xylene (X), -xylene (X), -xylene (X), and ethyl benzene (EB), are important raw materials in industry. The separation of xylene isomers has been recognized as one of the "seven chemical separations to change the world". However, because of their similar physicochemical properties, totally separating four xylene isomers has remained a big challenge until now.
View Article and Find Full Text PDFAnal Chem
January 2025
School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu 221116, China.
Conventional solid/liquid electrochemical interfaces typically encounter challenges with impeded mass transport for poor electrochemical quantification due to the intricate pathways of reactants from the bulk solution. To address this issue, this work reports an innovative approach integrating a target-activated DNA framework nanomachine with electrochemically driven metal-organic framework (MOF) conversion for self-sacrificial biosensing. The presence of the target biomarker serotonin initiates the DNA framework nanomachine by an entropy-driven circuit to form a cross-linked nanostructure and subsequently release the Fe-MOF probe.
View Article and Find Full Text PDFMater Horiz
January 2025
State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, 710049, P. R. China.
Integrated stretchable devices, containing soft modules, rigid modules, and encapsulation modules, are of potential use in implantable bioelectronics and wearable devices. However, such systems often suffer from electrical deterioration due to debonding failure at the connection between rigid and soft modules induced by severe stress concentration, limiting their practical implementation. Here, we report a highly conductive and adhesive bilayer interface that can reliably connect soft-soft modules and soft-rigid modules together by simply pressing without conductive pastes.
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