Iron chalcogenide superconductors have become one of the most investigated superconducting materials in recent years due to high upper critical fields, competing interactions and complex electronic and magnetic phase diagrams. The structural complexity, defects and atomic site occupancies significantly affect the normal and superconducting states in these compounds. In this work we review the vortex behavior, critical current density and high magnetic field pair-breaking mechanism in iron chalcogenide superconductors. We also point to relevant structural features and normal-state properties.
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http://dx.doi.org/10.1088/1468-6996/13/5/054305 | DOI Listing |
J Phys Chem A
January 2025
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.
Atomically precise nanoclusters (NCs) are promising building blocks for designing materials and interfaces with unique properties. By incorporating heteroatoms into the core, the electronic and magnetic properties of NCs can be precisely tuned. To accurately predict these properties, density functional theory (DFT) is often employed, making the rigorous benchmarking of DFT results particularly important.
View Article and Find Full Text PDFMicroorganisms
September 2024
Department of Microbiology, University of Massachusetts Amherst, Amherst, MA 01003, USA.
Acid mine drainage (AMD) pollutes natural waters, but some impacted systems show natural attenuation. We sought to identify the biogeochemical mechanisms responsible for the natural attenuation of AMD. We hypothesized that biogenic sulfide-mediated iron reduction is one mechanism and tested this in an experimental model system.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Engineering Research Center of Carbon Neutrality, Anhui Key Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, P. R. China.
The development of non-copper-based materials for CO electroreduction to ethanol with high selectivity at large current density is highly desirable, but still a great challenge. Herein, we report iron group metal ions of M (M=Fe, Co, or Ni)-doped amorphous/crystalline SnSe/SnSe nanorod/nanosheet hierarchical structures (a/c-SnSe/SnSe) for selective CO electroreduction to ethanol. Iron group metal ions doping induces multiple active sites at the interface of M-doped SnSe/SnSe p-n heterojunction, which strengthens *CO intermediate binding for further C-C coupling to eventual ethanol generation.
View Article and Find Full Text PDFChem Asian J
January 2025
Department of Chemistry, Malaviya National Institute of Technology Jaipur, JLN Marg, Jaipur, Rajasthan, 302017, India.
With the interest and knowing the importance of ferrocenyl conjugates, a direct amidation of ferrocenyl aldehyde has been developed under feasible conditions. Varieties of amines has been oxidatively coupled with ferrocene aldehyde in the presence of highly economical and robustly stable iron chalcogenide ironcarbonyl clusters [FeE(CO), E= S, Se, and Te] and TBHP. The reaction worked in greener solvent water at a moderate temperature of 70 °C and the ferrocenyl-amides in just 30 minutes.
View Article and Find Full Text PDFMaterials (Basel)
June 2024
Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China.
Iron-chalcogenide superconductors continue to captivate researchers due to their diverse crystalline structures and intriguing superconducting properties, positioning them as both a valuable platform for theoretical investigations and promising candidates for practical applications. This review begins with a comprehensive overview of the fabrication techniques employed for various iron-chalcogenide superconductors, accompanied by a summary of their phase diagrams. Subsequently, it delves into the upper critical field, anisotropy, and critical current density.
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