Graphene-based nano-objects such as nanotrenches, nanowires, nanobelts and nanoscale superstructures have been grown by surface segregation and precipitation on carbon-doped mono- and polycrystalline nickel substrates in ultrahigh vacuum. The dominant morphologies of the nano-objects were nanowire and nanosheet. Nucleation of graphene sheets occurred at surface defects such as step edges and resulted in the directional growth of nanowires. Surface analysis by scanning tunneling microscopy (STM) has clarified the structure and functionality of the novel nano-objects at atomic resolution. Nanobelts were detected consisting of bilayer graphene sheets with a nanoscale width and a length of several microns. Moiré patterns and one-dimensional reconstruction were observed on multilayer graphite terraces. As a useful functionality, application to repairable high-resolution STM probes is demonstrated.
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http://dx.doi.org/10.1088/1468-6996/12/4/044611 | DOI Listing |
Anal Chem
January 2025
School of Optoelectronic Engineering and Instrumentation Science, Dalian University of Technology, Dalian, Liaoning 116024, China.
A highly sensitive trace gas sensing system based on carbon black absorption enhanced photoacoustic (PA) spectroscopy (PAS) is reported. A carbon black sheet and a fiber-optic cantilever microphone (FOCM) are integrated to form a fiber-optic cantilever spectrophone (FOCS). The gas concentration is obtained by measuring the acoustic wave amplitude generated by the carbon black sheet, which absorbs the laser passing through the interest gas.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Chemical Engineering, Dr B R Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India.
Antimicrobial polymeric coatings rely not only on their surface functionalities but also on nanoparticles (NPs). Antimicrobial coatings gain their properties from the addition of NPs into a polymeric matrix. NPs that have been used include metal-based NPs, metal oxide NPs, carbon-based nanomaterials, and organic NPs.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Institute of Chemistry, St. Petersburg State University, 199034 St. Petersburg, Russia.
Deep eutectic solvents (DES) have emerged as versatile, sustainable media for the synthesis of nanomaterials due to their low toxicity, tunability, and biocompatibility. This study develops a one-step method to modify commercially available screen-printed electrodes (SPE) using laser-induced pyrolysis of DES, consisting of choline chloride and tartaric acid with dissolved nickel acetate and dispersed graphene. The electrodes were patterned using a 532 nm continuous-wave laser for the in situ formation of Ni nanoparticles decorated on graphene sheets directly on the SPE surface (Ni-G/SPE).
View Article and Find Full Text PDFMicromachines (Basel)
December 2024
Electronic Convergence Division, Korea Institute of Ceramic Engineering & Technology, 101, Soho-Ro, Jinju 52851, Republic of Korea.
Developing thin-film sheets made of oxide-based solid electrolytes is essential for fabricating surface-mounted ultracompact multilayer oxide solid-state batteries. To this end, solid-electrolyte slurry must be optimized for excellent dispersibility. Although oxide-based solid electrolytes for multilayer structures require sintering, high processing temperatures cause problems such as Li-ion volatilization and reactions with graphite anodes.
View Article and Find Full Text PDFMicromachines (Basel)
December 2024
Department of Optometry, Faculty of Allied Health Sciences, University of Sri Jayewardenepura, Nugegoda 10250, Sri Lanka.
Gas sensors play a vital role in detecting gases in the air, converting their concentrations into electrical signals for industrial, environmental, and safety applications. This study used density functional theory methods to explore the mechanism and sensitivity of a PdO-graphene composite sensor towards various gases (CO, NO, NO, HS, and Cl). All calculations, including structure, energy, and frequency optimizations, were performed using the Gaussian software with appropriate configurations and basis sets.
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