Selective One-Pot Production of High-Grade Diesel-Range Alkanes from Furfural and 2-Methylfuran over Pd/NbOPO.

ChemSusChem

Shanghai Key Laboratory of Functional Materials Chemistry and Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science of Technology, No. 130, Meilong Road, Shanghai, 200237, P.R. China.

Published: February 2017

AI Article Synopsis

  • A new method was developed for creating high-quality diesel-range alkanes from biomass materials like furfural and 2-methylfuran (2-MF) using a one-pot process.
  • This process combines two steps: hydroxyalkylation/alkylation (HAA) and hydrodeoxygenation (HDO) over a special catalyst (Pd/NbOPO).
  • With the right conditions, this method achieved a total yield of 89.1% for producing diesel-range alkanes from the starting materials.

Article Abstract

A one-pot method for the selective production of high-grade diesel-range alkanes from biomass-derived furfural and 2-methylfuran (2-MF) was developed by combining the hydroxyalkylation/alkylation (HAA) condensation of furfural with 2-MF and the subsequent hydrodeoxygenation (HDO) over a multifunctional Pd/NbOPO catalyst. The effects of various reaction conditions as well as a variety of solid-acid catalysts and metal-loaded NbOPO catalysts were systematically investigated to optimize the reaction conditions for both reactions. Under the optimal reaction conditions up to 89.1 % total yield of diesel-range alkanes was obtained from furfural and 2-MF by this one-pot method.

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http://dx.doi.org/10.1002/cssc.201601522DOI Listing

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