Stability of Cassie-Baxter wetting states on microstructured surfaces.

Phys Rev E

Institute of Biomechanics and Medical Engineering, Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China.

Published: October 2016

A stable Cassie-Baxter (CB) wetting state is indispensable for the superhydrophobicity of solid surfaces. In this paper, we analyze the equilibrium and stability of CB wetting states. Using an energy approach, the stability criteria of CB wetting states are established for solid surfaces with either two- or three-dimensional symmetric microstructures. A generic method is presented to calculate the critical pressure at which the CB state on a microstructured solid surface collapses. The method holds for microstructures with arbitrary generatrix, and explicit solutions are derived for a few representative microstructures with a straight or circular generatrix. In addition, some possible strategies are proposed to design surface structures with stable CB wetting states from the viewpoints of geometry and chemistry.

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http://dx.doi.org/10.1103/PhysRevE.94.042801DOI Listing

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