A stable Cassie-Baxter (CB) wetting state is indispensable for the superhydrophobicity of solid surfaces. In this paper, we analyze the equilibrium and stability of CB wetting states. Using an energy approach, the stability criteria of CB wetting states are established for solid surfaces with either two- or three-dimensional symmetric microstructures. A generic method is presented to calculate the critical pressure at which the CB state on a microstructured solid surface collapses. The method holds for microstructures with arbitrary generatrix, and explicit solutions are derived for a few representative microstructures with a straight or circular generatrix. In addition, some possible strategies are proposed to design surface structures with stable CB wetting states from the viewpoints of geometry and chemistry.
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http://dx.doi.org/10.1103/PhysRevE.94.042801 | DOI Listing |
Adv Mater
January 2025
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences (CAS), Ningbo, 315201, China.
Reducing excess electrolytes offers a promising approach to improve the specific energy of electrochemical energy storage devices. However, using lean electrolytes presents a significant challenge for porous electrode materials due to heterogeneous wetting. The spontaneous wetting of nano- or meso-pores within particles, though seldom discussed, adversely affects wetting under lean electrolyte conditions.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physics, College of Science, University of Thi-Qar, Nasiriya, Iraq.
This work studies the generation of the orbital angular momentum (OAM) beam in the double quantum dot-metal nanoparticle (DQD-MNP) system under the application of the OAM beam. First, an analytical model is derived to attain the relations of probe and generated fields as a distance function in the DQD-MNP system under OAM applied field and spontaneously generated coherence (SGC) components. The calculation here is of material property; it differs from others by calculating energy states of the DQDs and the computation of the transition momenta between quantum dot (QD)-QD and QD-wetting layer (WL) transitions.
View Article and Find Full Text PDFAcc Chem Res
January 2025
Helmholtz Institute Ulm (HIU) Electrochemical Energy Storage, Helmholtzstrasse 11, 89081 Ulm, Germany.
ConspectusLithium-ion batteries (LIBs) based on graphite anodes are a widely used state-of-the-art battery technology, but their energy density is approaching theoretical limits, prompting interest in lithium-metal batteries (LMBs) that can achieve higher energy density. In addition, the limited availability of lithium reserves raises supply concerns; therefore, research on postlithium metal batteries is underway. A major issue with these metal anodes, including lithium, is dendritic formation and insufficient reversibility, which leads to safety risks due to short circuits and the use of flammable electrolytes.
View Article and Find Full Text PDFJ Environ Manage
January 2025
School of Water Conservancy and Transportation, Zhengzhou University, Zhengzhou City, 450001, Henan Province, China. Electronic address:
Enhancing the understanding of the rainfall-runoff temporal dynamics in semi-arid and semi-humid regions is crucial for flood disaster mitigation. Loess Plateau is a unique environment within semi-arid and semi-humid regions, characterized by its deep loess soil, prevalent short-duration intense rainfall, and changes in underlying surface conditions. In this research, 25 catchments from the Loess Plateau were chosen to examine the temporal variations in event runoff responses across different time scales.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Centre for Nanomaterials and Biotechnology, Faculty of Science, University of Jan Evangelista Purkyně, Pasteurova 15, 400 96 Ústí nad Labem, Czech Republic.
Surface modification of various polymer foils was achieved by UV activation and chemical grafting with cysteamine to improve surface properties and antimicrobial efficacy. UVC activation at 254 nm led to changes in surface wettability and charge density, which allowed the introduction of amino and thiol functional groups by cysteamine grafting. X-ray photoelectron spectroscopy (XPS) confirmed increased nitrogen and sulfur content on the modified surfaces.
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