We have designed and synthesized the first examples of fluorescent chemosensors based on octa-BODIPY decorated dendrimeric cyclotetraphosphazenes. The structures these synthesized compounds were verified by H, C, P NMR spectroscopies and UV-vis electronic absorption spectra. The photophysical and metal sensing properties in THF solutions of dendrimeric cyclotetraphosphazenes (OBCP 1-3) were investigated by fluorescence spectroscopy. OBCP 1-3 showed strong absorption in the 500-640nm region with high molar extinction coefficients. Additionally, octa-BODIPY decorated dendrimeric cyclotetraphosphazenes are candidate for fluorescent chemosensor for Co showing high selectivity with a low limit of detection.
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http://dx.doi.org/10.1016/j.saa.2016.10.052 | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
September 2019
Department of Chemistry, Faculty of Science, Gebze Technical University, Gebze, Kocaeli, Turkey. Electronic address:
Novel fluorescent anthracene-decorated cyclotri- and cyclotetraphosphazenes (5 and 6) are designed and synthesized, and their chemosensor behaviors against nitroaromatic compounds are examined by UV/Vis and fluorescence spectroscopies for addressing the sensors with cyclophosphazenes for 2,4,6-trinitrotoluene detection. The fluorescence intensities of (5 and 6) are found to be selectively quenched by only 2,4,6-trinitrotoluene through the non-covalent π⋯π stacking interactions between anthracene-substituted cyclophosphazenes and 2,4,6-trinitrotoluene. In addition, cyclic voltammetry and theoretical calculation of novel sensor systems are studied.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2017
Department of Chemistry, Gebze Technical University, Gebze, 41400 Kocaeli, Turkey.
We have designed and synthesized the first examples of fluorescent chemosensors based on octa-BODIPY decorated dendrimeric cyclotetraphosphazenes. The structures these synthesized compounds were verified by H, C, P NMR spectroscopies and UV-vis electronic absorption spectra. The photophysical and metal sensing properties in THF solutions of dendrimeric cyclotetraphosphazenes (OBCP 1-3) were investigated by fluorescence spectroscopy.
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