Octa-BODIPY derivative dendrimeric cyclotetraphosphazenes; photophysical properties and fluorescent chemosensor for Co ions.

Spectrochim Acta A Mol Biomol Spectrosc

Department of Chemistry, Gebze Technical University, Gebze, 41400 Kocaeli, Turkey.

Published: February 2017

We have designed and synthesized the first examples of fluorescent chemosensors based on octa-BODIPY decorated dendrimeric cyclotetraphosphazenes. The structures these synthesized compounds were verified by H, C, P NMR spectroscopies and UV-vis electronic absorption spectra. The photophysical and metal sensing properties in THF solutions of dendrimeric cyclotetraphosphazenes (OBCP 1-3) were investigated by fluorescence spectroscopy. OBCP 1-3 showed strong absorption in the 500-640nm region with high molar extinction coefficients. Additionally, octa-BODIPY decorated dendrimeric cyclotetraphosphazenes are candidate for fluorescent chemosensor for Co showing high selectivity with a low limit of detection.

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http://dx.doi.org/10.1016/j.saa.2016.10.052DOI Listing

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We have designed and synthesized the first examples of fluorescent chemosensors based on octa-BODIPY decorated dendrimeric cyclotetraphosphazenes. The structures these synthesized compounds were verified by H, C, P NMR spectroscopies and UV-vis electronic absorption spectra. The photophysical and metal sensing properties in THF solutions of dendrimeric cyclotetraphosphazenes (OBCP 1-3) were investigated by fluorescence spectroscopy.

View Article and Find Full Text PDF

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