This study investigated the nature of infants' difficulty understanding references to hidden inaccessible objects. Twelve-month-old infants (N = 32) responded to the mention of objects by looking at, pointing at, or approaching them when the referents were visible or accessible, but not when they were hidden and inaccessible (Experiment I). Twelve-month-olds (N = 16) responded robustly when a container with the hidden referent was moved from a previously inaccessible position to an accessible position before the request, but failed to respond when the reverse occurred (Experiment II). This suggests that infants might be able to track the hidden object's dislocations and update its accessibility as it changes. Knowing the hidden object is currently inaccessible inhibits their responding. Older, 16-month-old (N = 17) infants' performance was not affected by object accessibility.
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Spectrochim Acta A Mol Biomol Spectrosc
December 2024
Institute of Heritage Science, National Research Council (CNR ISPC), Via Cozzi 53, 20125 Milano, Italy. Electronic address:
The preservation of paper-based archival documents is crucial for safeguarding historical and cultural heritage. Some records possess visually inaccessible text or images because of previous conservation measures, their method of construction, or historic damage. Micro-spatially Offset Raman Spectroscopy (micro-SORS) has emerged as a promising method for probing below or through opaque material substrates non-invasively.
View Article and Find Full Text PDFCommun Chem
December 2024
Section Biomedical Imaging, Molecular Imaging North Competence Center (MOIN CC), Department of Radiology and Neuroradiology, University Medical Center Kiel, Kiel University, Am Botanischen Garten 14, 24118, Kiel, Germany.
The signal amplification by reversible exchange process (SABRE) enhances NMR signals by unlocking hidden polarization in parahydrogen through interactions with to-be-hyperpolarized substrate molecules when both are transiently bound to an Ir-based organometallic catalyst. Recent efforts focus on optimizing polarization transfer from parahydrogen-derived hydride ligands to the substrate in SABRE. However, this requires quantitative information on ligand exchange rates, which common NMR techniques struggle to provide.
View Article and Find Full Text PDFNat Commun
November 2024
Department of Physics and Astronomy, Rutgers University, Piscataway, NJ, USA.
J Am Chem Soc
November 2024
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City 350207, China.
Covalent organic frameworks (COFs) can be developed for molecular confinement and separation. However, their proximate π stacks limit the interlayer distance to be only 3-6 Å, which is too small for guests to enter. As a result, COFs block access to the - space and limit guest entry/exit strictly to only the pores along the direction.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
November 2024
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai NewCity, Fuzhou, 350207, China.
Covalent organic frameworks with unique π architectures and pores could be developed as photocatalysts for transformations. However, they usually form π-stacking layers, so that only surface layers function in photocatalysis. Here we report a strategy for developing vertically expanded frameworks to expose originally inaccessible active sites hidden in layers to catalysis.
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