Engineering of photonics for antireflection and electronics for extraction of the hole using 2.5 nm of a thin Au layer have been performed for two- and four-terminal tandem solar cells using CHNHPbI perovskite (top cell) and p-type single crystal silicon (c-Si) (bottom cell) by mechanically stacking. Highly transparent connection multilayers of evaporated-Au and sputtered-ITO films were fabricated at the interface to be a point-contact tunneling junction between the rough perovskite and flat silicon solar cells. The mechanically stacked tandem solar cell with an optimized tunneling junction structure was ⟨perovskite for the top cell/Au (2.5 nm)/ITO (154 nm) stacked-on ITO (108 nm)/c-Si for the bottom cell⟩. It was confirmed the best efficiency of 13.7% and 14.4% as two- and four-terminal devices, respectively.
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http://dx.doi.org/10.1021/acsami.6b07781 | DOI Listing |
Nat Commun
January 2025
MOE International Joint Laboratory of Materials Microstructure, Institute for New Energy Materials and Low Carbon Technologies, Analysis and Testing Center, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China.
CO conversion to CHOH under mild conditions is of particular interest yet rather challenging. Both electro- and thermo-catalytic CO reduction to CHOH can only produce CHOH in low concentration (typically mixed with water), requiring energy-intensive purification processes. Here we design a sun-simulated-driven tandem catalytic system comprising CO electroreduction to syngas, and further photothermal conversion into high-purity CHOH (volume fraction > 97%).
View Article and Find Full Text PDFAdv Mater
January 2025
School of Pharmaceutical and Chemical Engineering, Taizhou University, Jiaojiang, 318000, P. R. China.
Efficient charge separation at the semiconductor/cocatalyst interface is crucial for high-performance photoelectrodes, as it directly influences the availability of surface charges for solar water oxidation. However, establishing strong molecular-level connections between these interfaces to achieve superior interfacial quality presents significant challenges. This study introduces an innovative electrochemical etching method that generates a high concentration of oxygen vacancy sites on BiVO surfaces (Ov-BiVO), enabling interactions with the oxygen-rich ligands of MIL-101.
View Article and Find Full Text PDFAdv Mater
January 2025
Department of Materials Science and Engineering, Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong, Southern University of Science and Technology, Shenzhen, 518055, China.
Nickel oxide (NiO) is considered as a potential hole transport material in the fabrication of lead-tin (Pb-Sn) perovskite solar cells (PSCs) for tandem applications. However, the energy level mismatch and unfavorable redox reactions between Ni species and Sn at the NiO/perovskite interface pose challenges. Herein, high-performance Pb-Sn-based inorganic PSCs are demonstrated by modulating the NiO/perovskite interface with a multifunctional 4-aminobenzenesulfonic acid (4-ABSA) interlayer.
View Article and Find Full Text PDFEnviron Pollut
January 2025
Beijing Institute of Occupational Disease Prevention and Control, Beijing 100093, China. Electronic address:
Studies have shown that the presence of allergens, including insecticides, significantly increases the risk of occupational allergic diseases among solar greenhouse workers. However, no studies have yet investigated the relationship between organophosphorus pesticide use by greenhouse workers and allergic diseases, and the role of the flora in this context remains unclear. Therefore, this study aimed to investigate the relationship between combined exposure to organophosphorus pesticides (OPs) and Glyphosate (GLY) and changes in total immunoglobulin E (IgE) levels, as well as to analyze the role of nasal flora in allergic status.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, School of Materials Science and Engineering, Hebei University of Technology, Tianjin, China.
Interfacial trap-assisted nonradiative recombination hampers the development of metal halide perovskite solar cells (PSCs). Herein, we report a rationally designed universal passivator to realize highly efficient and stable single junction and tandem PSCs. Multiple defects are simultaneously passivated by the synergistic effect of anion and cation.
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