A novel type of phosphoric acid catalyst with enhanced reactivity is reported. These compounds possess one or two positively charged centers which electrostatically activate them. This is illustrated in several bond-forming transformations including Friedel-Crafts and Diels-Alder reactions as well as a ring-opening polymerization. Rate accelerations corresponding to orders of magnitude are observed.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.orglett.6b02750 | DOI Listing |
Publication Analysis
Top Keywords
electrostatically enhanced
4
enhanced phosphoric
4
phosphoric acids
4
acids tool
4
tool brønsted
4
brønsted acid
4
acid catalysis
4
catalysis novel
4
novel type
4
type phosphoric
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!