Both Schaefer-Bergmann diffraction and resonant ultrasound spectroscopy were used to measure the six independent elastic-stiffness coefficients of the trigonal, non-piezoelectric crystal α-BaBO. The two measurement sets resulted in a root-mean-square variance of 1.2%. This paper provides a detailed analysis of the two different measurement techniques and discusses the similarities and differences.
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http://dx.doi.org/10.1121/1.4964823 | DOI Listing |
Sci Rep
January 2025
Ali I. Al-Naimi Petroleum Engineering Research Center, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.
Microbial impacts on early carbonate diagenesis, particularly the formation of Mg-carbonates at low temperatures, have long eluded scientists. Our breakthrough laboratory experiments with two species of halophilic aerobic bacteria and marine carbonate grains reveal that these bacteria created a distinctive protodolomite (disordered dolomite) rim around the grains. Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD) confirmed the protodolomite formation, while solid-state nuclear magnetic resonance (NMR) revealed bacterial interactions with carboxylated organic matter, such as extracellular polymeric substances (EPS).
View Article and Find Full Text PDFNat Nanotechnol
January 2025
Wellman Center for Photomedicine, Massachusetts General Hospital, Cambridge, MA, USA.
The ultimate limit for laser miniaturization would be achieving lasing action in the lowest-order cavity mode within a device volume of ≤(λ/2n), where λ is the free-space wavelength and n is the refractive index. Here we highlight the equivalence of localized surface plasmons and surface plasmon polaritons within resonant systems, introducing nanolasers that oscillate in the lowest-order localized surface plasmon or, equivalently, half-cycle surface plasmon polariton. These diffraction-limited single-mode emitters, ranging in size from 170 to 280 nm, harness strong coupling between gold and InGaAsP in the near-infrared (λ = 1,000-1,460 nm), away from the surface plasmon frequency.
View Article and Find Full Text PDFInt J Pharm
December 2024
Sciences Center of Imperatriz, Federal University of Maranhão - UFMA, 65900-410, Imperatriz, MA, Brazil. Electronic address:
This study reports the synthesis and the experimental-theoretical characterization of a new coamorphous system consisting of ethionamide (ETH) and mandelic acid (MND) as a coformer. The solid dispersion was synthesized using the slow solvent evaporation method in an ethanolic medium. The structural, vibrational, and thermal properties of the system were characterized.
View Article and Find Full Text PDFJ Chem Theory Comput
January 2025
State Key Laboratory for Mesoscopic Physics and Collaborative Innovation Center of Quantum Matter, School of Physics, Peking University, Beijing 100871, China.
With the advancement of high harmonic generation and X-ray free-electron lasers (XFELs) to the attosecond domain, the studies of the ultrafast electron and spin dynamics became possible. Yet, the methods for efficient control and measurement of the quantum state are to be further developed. In this publication, we propose using magnetic X-ray scattering (MXS) for resolving the molecular spin-state dynamics and establish a complete protocol to simulate MXS diffraction patterns in molecules with ab initio quantum chemistry based on the multiconfigurational method.
View Article and Find Full Text PDFFront Chem
December 2024
Department of Chemistry, University of Wyoming, Laramie, WY, United States.
Covalent integration of polymers and porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs), represent a promising strategy for overcoming the existing limitations of traditional porous materials. This integration allows for the combination of the advantages of polymers, i.e.
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