The impact of torrefaction and low-temperature carbonization on the properties of biomass wastes from Arundo donax L. and Phoenix canariensis was studied. Thermal treatments were performed at temperatures from 200°C to 350°C during 15 to 90min and temperature was the parameter that more influenced mass and energy yields as well as biochar composition. Torrefaction reduced moisture, volatile matter, O/C and H/C ratios of the biomass, while increasing heating value, ash content and fixed carbon. For torrefaction at 250°C or higher temperatures grindability of the biochars was significantly improved. The low volatile matter contents and high ash contents of these biochars restricts their use as solid fuels but they can be valorized otherwise. Raw biomasses and the biochars torrefied at 200°C could remove methylene blue from an aqueous solution, in fast adsorption test with a contact time of only 3s, with efficiencies higher than 50%.
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http://dx.doi.org/10.1016/j.biortech.2016.10.046 | DOI Listing |
Sci Total Environ
December 2024
Research Center for Smart Sustainable Circular Economy, Tunghai University, Taichung 407, Taiwan; Department of Chemical and Materials Engineering, Tunghai University, Taichung 407, Taiwan.
Research on plastic pollution is crucial, particularly with the recent emphasis on converting waste plastics into oil for sustainable energy. Very few studies have utilized artificial neural network (ANN) modeling for plastic thermal conversion, such as predicting fuel yield from mixed plastics and performing sensitivity analyses to identify which plastics produce more oil. Meanwhile, no study has conducted a comparative analysis of different models for catalytic and non-catalytic thermal conversion of various plastics, nor has a sensitivity analysis of process parameters using ANN for oil production.
View Article and Find Full Text PDFJ Environ Manage
December 2024
State Key Laboratory of Low-carbon Smart Coal-fired Power Generation and Ultra-clean Emission, School of Energy and Environment, Southeast University, Nanjing, 210096, China; Special Equipment Safety Supervision Inspection Institute of Jiangsu Province, Nanjing, 210036, China.
Finding alternative energy sources and reducing the impact of waste on the environment are pressing global challenges. Crab shells possess the dual characteristics of a pollutant and a resource; therefore, transforming them into clean energy is an urgent issue that needs to be addressed for reducing environmental pollution. This study uses microwave torrefaction to treat crab shell waste efficiently and optimizes the torrefaction conditions through response surface methodology to rapid prepare derived fuel.
View Article and Find Full Text PDFMolecules
September 2024
Centro de Estudos Florestais, Laboratório Associado TERRA, Instituto Superior de Agronomia, Universidade de Lisboa, 1349-017 Lisboa, Portugal.
This study aimed to evaluate the influence in torrefaction of the chemical structure of biomasses from nine poplar commercial SRC clones, evaluated through analytical pyrolysis. The chemical data were integrated into a dataset including LHV gain, representative of torrefaction aptitude and six chemical variables obtained through analytical pyrolysis, which were: (i) CHCl extractives; (ii) total extractives; (iii) Py-lignin; (iv) holocellulose; (v) (syringil/guaiacyl) ratio; and (vi) (pentosan/hexosan) ratio. Significant univariate and bivariate linear relations were obtained with LHV gain from torrefaction as dependent variable vs.
View Article and Find Full Text PDFSci Rep
September 2024
Department of Mining, Metallurgy and Geology Engineering, University of Guanajuato, 36020, Guanajuato, Guanajuato, Mexico.
Energy Fuels
July 2024
Instituto de Carboquímica (ICB-CSIC). Miguel Luesma Castán 4, 50018 Zaragoza, Spain.
The innovative Biomass Chemical Looping Gasification (BCLG) process uses two reactors (fuel and air reactors) to generate nitrogen-free syngas with low tar content under autothermal conditions. A solid oxygen carrier supplies the oxygen for partial oxidation of the fuel. This study investigated the BCLG process, conducted over 25 h of continuous operation at 20 kW scale, using ilmenite as the oxygen carrier and wheat straw pellets as fuel (WSP).
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