This work investigates the hydrothermal liquefaction (HTL) of Cyanidioschyzon merolae algal species under various reaction temperatures and catalysts. Liquefaction of microalgae was performed with 10% solid loading for 30min at temperatures of 180-300°C to study the influences of two base and two acid catalysts on HTL product fractions. Maximum biocrude oil yield of 16.98% was obtained at 300°C with no catalyst. The biocrude oil yield increased to 22.67% when KOH was introduced into the reaction mixture as a catalyst. The algal biocrude and biochar has a higher heating values (HHV) of 32.22MJkg and 20.78MJkg respectively when no catalyst was used. Gas chromatography time of flight mass spectrometry (GC/TOFMS) was employed to analyze the biocrude oil composition, and elemental analysis was performed on the algae, biocrude and biochar samples. Analysis of the HTL aqueous phase revealed the presence of valuable products.
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http://dx.doi.org/10.1016/j.biortech.2016.10.022 | DOI Listing |
Nat Commun
January 2025
Laboratory of Environment-Enhancing Energy (E2E), College of Water Resources and Civil Engineering, China Agricultural University, Beijing, 100083, China.
Biocrude derived from biomass via hydrothermal liquefaction (HTL) is a sustainable substitute for petroleum to obtain energy and biochemicals. Upgrading biocrude inevitably faces the trade-off between consuming large amounts of hydrogen via hydrotreating and high yield of solid residue without additional hydrogen. In this work, we report a non-hydrogenated refinery paradigm for nearly complete valorization (~90%), via co-generating green coal and bio-lubricant.
View Article and Find Full Text PDFSci Rep
January 2025
Process and Energy Department, University of Technology of Delft, Leeghwaterstraat 39, 2628 CB, Delft, The Netherlands.
An urgent ecological issue is the threat posed by invasive species, which are becoming more widespread especially in Africa. These encroachments damage ecosystems, pose a threat to biodiversity, and outcompete local plants and animals. This article focuses on converting Acacia Mellifera from Namibia, commonly known as encroacher bush (EB) into high-quality drop-in intermediates for the chemical and transport industry via hydrothermal liquefaction (HTL).
View Article and Find Full Text PDFBMC Biotechnol
November 2024
Biochemical Process Engineering, Division of Chemical Engineering, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, Luleå, SE-971 87, Sweden.
Acc Chem Res
December 2024
Penn State University, Chemical Engineering Department, University Park, Pennsylvania 16802, United States.
Sci Rep
October 2024
Montana Tech Nanotechnology Laboratory, Montana Technological University, Butte, MT, 59701, USA.
Electrospinning is utilized to fabricate catalytic nanofiber scaffold for biocrude upgrading in hydrodeoxygenation (HDO) following computational studies suggesting the need for nano-catalysts for efficient HDO conversion and selectivity. Here, Pt-TiO nanofibers are fabricated through electrospinning, followed by wet impregnation with a heteropoly acid (HPA), tungstosilicic acid. Intensive heat treatments were incorporated during and after processes to obtain a HPA doped Pt-TiO nano-catalyst.
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