Stabilization of carbon dioxide and chromium slag via carbonation.

Environ Technol

a MOE Key Laboratory of Soft Soils and Geoenvironmental Engineering, Department of Environmental Engineering, Laboratory of Electrochemistry and Energy Storage, State Key laboratory of Clean Energy Utilization , Zhejiang University, Hangzhou , People's Republic of China.

Published: August 2017

As the main greenhouse gas, CO is considered as a threat in the context of global warming. Many available technologies to reduce CO emission was about CO separation from coal combustion and geological sequestration. However, how to deal with the cost-effective storage of CO has become a new challenge. Moreover, chromium pollution, the treatment of which requires huge energy consumption, has attracted people's widespread attention. This study is aimed to develop the sequestration of CO via chromium slag. A dynamic leaching experiment of chromium slag was designed to testify the ability of CO adsorption onto chromium slag and to release Cr(VI) for stabilization. The results showed that the accumulative amounts of Cr(VI) were ca. 2.6 mg/g released from the chromium slag after 24 h of leaching. In addition, ca. 89 mg/g CO was adsorbed by using pure CO in the experiment at 12 h. Calcite is the only carbonate species in the post-carbonated slag analyzed by powder X-ray diffraction and thermal analysis. The approach provides the feasibility of the utilization of chromium slag and sequestration of the carbon dioxide at the same time at ordinary temperatures and pressures.

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http://dx.doi.org/10.1080/09593330.2016.1244566DOI Listing

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