Reaction of C with Inactive Secondary Amines and Aldehydes and the Cu(OAc)-Promoted Regioselective Intramolecular C-H Functionalization of the Generated Fulleropyrrolidines.
J Org Chem
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China.
Published: November 2016
The thermal reaction of C with aromatic aldehydes and inactive secondary amines for the stereoselective synthesis of trans-1,2,5-trisubstituted fulleropyrrolidines has been developed. Moreover, when an o-hydroxyl group was located at the phenyl ring of the generated fulleropyrrolidines, the Cu(OAc)-promoted regioselective intramolecular C-O coupling reaction occurred to generate unique tricycle-fused fullerene derivatives.
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