Hydrogen is often described as the fuel of the future, especially for application in hydrogen powered fuel-cell vehicles (HFCV's). However, its widespread implementation in this role has been thwarted by the lack of a lightweight, safe, on-board hydrogen storage material. Here we show that benign, readily-available hydrocarbon wax is capable of rapidly releasing large amounts of hydrogen through microwave-assisted catalytic decomposition. This discovery offers a new material and system for safe and efficient hydrogen storage and could facilitate its application in a HFCV. Importantly, hydrogen storage materials made of wax can be manufactured through completely sustainable processes utilizing biomass or other renewable feedstocks.
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http://dx.doi.org/10.1038/srep35315 | DOI Listing |
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January 2025
Institute of Smart City and Intelligent Transportation, Southwest Jiaotong University, Chengdu, 610031, China.
Although carbon-based supercapacitors (SCs) hold the advantages of high-power and large-current characteristics, they are difficult to realize ultrahigh-power density (> 200 kW kg) and maintain almost constant energy density at ultrahigh power. This limitation is mainly due to the difficulty in balancing the structural order related to the electrical conductivity of carbon materials and the structural disorder related to the pore structure. Herein, we design a novel super-structured tubular carbon (SSTC) with a crosslinked porous conductive network to solve the structure order-disorder tradeoff effect in carbon materials.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Light Industry and Food Engineering, Nanjing Forestry University, Nanjing 210037, China. Electronic address:
TEMPO-CNF film modified by two-dimension transition metal MXene has certain antibacterial properties. However, the problem of long-lasting stability greatly restricts the feasibility of long-term use of the composite film. Here, we introduced polyaniline (PANI) as a modifying molecule, which was electrostatically adsorbed on the surface of the MXene nanosheets to prevent its self-stacking and delay its oxidation.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
School of Food Science and Engineering, Ningxia University, Yinchuan, Ningxia 750021, China. Electronic address:
The ternary complex effectively prevents droplet aggregation, Ostwald ripening, and phase separation through its gel network, thereby demonstrating its capability in bioactive compound delivery. In this work, the influence of varying chickpea protein isolate (CPI) levels on the microstructure, gel characteristics, stability and functional properties of grape seed proanthocyanidin (GSP) and konjac gum (KGM) stabilized ternary complexes was investigated. Visual appearance indicated the formation of a non-stratified ternary complex as the CPI enhanced to 3-4 %.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Chemistry, Dalian University of Technology, Dalian 116024 PR China. Electronic address:
The development of electrode materials for aqueous ammonium-ion supercapacitors (NH-SCs) has garnered significant attention in recent years. Poor intrinsic conductivity, sluggish electron transfer and ion diffusion kinetics, as well as structural degradation of vanadium oxides during the electrochemical process, pose significant challenges for their efficient ammonium-ion storage. In this work, to address the above issues, the core-shell VO·nHO@poly(3,4-ethylenedioxithiophene) composite (denoted as VOH@PEDOT) is designed and prepared by a simple agitation method to boost the ammonium-ion storage of VO·nHO (VOH).
View Article and Find Full Text PDFSci Total Environ
January 2025
School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China.
Ammonia (NH) holds promise as a carbon-free fuel. Blending it with highly reactive fuels could efficiently alleviate issues such as slow burning rates and narrow flammability ranges. Ethanol (CHOH) offers the advantage of carbon neutrality and has a high-octane rating.
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