Topology-dependent emissive properties of zirconium-based porphyrin MOFs.

Chem Commun (Camb)

Department of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, USA.

Published: October 2016

Highly ordered chromophoric linkers positioned within the metal-organic frameworks (MOFs) have the potential to mimic natural light-harvesting complexes. Herein we report topological control over the photophysical properties of MOFs via modular interchromophoric electronic coupling to manifest different steady-state singlet emission spectra and their corresponding fluorescence lifetimes.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c6cc07343cDOI Listing

Publication Analysis

Top Keywords

topology-dependent emissive
4
emissive properties
4
properties zirconium-based
4
zirconium-based porphyrin
4
porphyrin mofs
4
mofs highly
4
highly ordered
4
ordered chromophoric
4
chromophoric linkers
4
linkers positioned
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!