Exact symmetries in the velocity fluctuations of a hot Brownian swimmer.

Phys Rev E

Institut für Theoretische Physik, Universität Leipzig, Postfach 100 920, D-04009 Leipzig, Germany.

Published: September 2016

Symmetries constrain dynamics. We test this fundamental physical principle, experimentally and by molecular dynamics simulations, for a hot Janus swimmer operating far from thermal equilibrium. Our results establish scalar and vectorial steady-state fluctuation theorems and a thermodynamic uncertainty relation that link the fluctuating particle current to its entropy production at an effective temperature. A Markovian minimal model elucidates the underlying nonequilibrium physics.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevE.94.030602DOI Listing

Publication Analysis

Top Keywords

exact symmetries
4
symmetries velocity
4
velocity fluctuations
4
fluctuations hot
4
hot brownian
4
brownian swimmer
4
swimmer symmetries
4
symmetries constrain
4
constrain dynamics
4
dynamics test
4

Similar Publications

Effect of Exact Exchange on the Energy Landscape in Self-Consistent Field Theory.

J Chem Theory Comput

January 2025

Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, U.K.

Density functional approximations can reduce the spin symmetry breaking observed for self-consistent field (SCF) solutions compared to Hartree-Fock theory, but the amount of exact Hartree-Fock (HF) exchange appears to be a key determinant in broken symmetry. To elucidate the precise role of exact exchange, we investigate the energy landscape of unrestricted Hartree-Fock and Kohn-Sham density functional theory for benzene and square cyclobutadiene, which provide paradigmatic examples of closed-shell and open-shell electronic structures, respectively. We find that increasing the amount of exact exchange leads to more local SCF minima, which can be characterized as combinatorial arrangements of unpaired electrons in the carbon π system.

View Article and Find Full Text PDF

Stacking interactions are a recurring motif in supramolecular chemistry and biochemistry, where a persistent theme is a preference for parallel-displaced aromatic rings rather than face-to-face π-stacking. This is typically explained in terms of quadrupole-quadrupole interactions between the arene moieties but that interpretation is inconsistent with accurate calculations, which reveal that the quadrupolar picture is qualitatively wrong. At typical π-stacking distances, quadrupolar electrostatics may differ in sign from an exact calculation based on charge densities of the interacting arenes.

View Article and Find Full Text PDF

We report on a class of gapped projected entangled pair states (PEPS) with non-trivial Euler topology motivated by recent progress in band geometry. In the non-interacting limit, these systems have optimal conditions relating to saturation of quantum geometrical bounds, allowing for parent Hamiltonians whose lowest bands are completely flat and which have the PEPS as unique ground states. Protected by crystalline symmetries, these states evade restrictions on capturing tenfold-way topological features with gapped PEPS.

View Article and Find Full Text PDF

This study probes the vibronic interactions in the photoelectron spectra of CAlGe, exploring its six excited electronic states through an approach that combines the electronic structure calculations and the quantum nuclear dynamics. Central to this investigation is utilizing a model diabatic Hamiltonian, which allows for the exact evaluation of Hamiltonian parameters and fitting potential energy cuts (PECs). Notably, the analysis of these PECs uncovers pronounced nonadiabatic effects within the photoelectron spectra, emphasized by the presence of multiple conical intersections.

View Article and Find Full Text PDF

The nonintegrable higher spin Kitaev honeycomb model has an exact Z_{2} gauge structure, which exclusively identifies quantum spin liquid in the half-integer spin Kitaev model. But its constraints for the integer-spin Kitaev model are much limited, and even trivially gapped insulators cannot be excluded. The physical implications of exact Z_{2} gauge structure, especially Z_{2} fluxes, in integer-spin models remain largely unexplored.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!