We observe the hysteresis of a spontaneous symmetry breaking (SSB) transition in a parametrically modulated magneto-optical trap by sweeping the total number of atoms and study thermal hysteretic behavior in the system by measuring the scaling exponent of hysteresis. It is shown that the relaxation time of the order parameter in the SSB transition becomes larger near the critical number. The scaling exponent of the hysteresis area with number sweeping rate is found to be 0.64±0.04, which is consistent with the value in the mean-field model.
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http://dx.doi.org/10.1103/PhysRevE.94.032141 | DOI Listing |
J Chem Phys
January 2025
Université Paris-Saclay, UVSQ, CNRS, GEMaC, 45 Avenue des Etats Unis, 78035 Versailles, France.
Among the large family of spin-crossover (SCO) solids, recent investigations focused on polynuclear SCO materials, whose specific molecular configurations allow the presence of multi-step transitions and elastic frustration. In this contribution, we develop the first elastic modeling of thermal and dynamical properties of trinuclear SCO solids. For that, we study a finite SCO open chain constituted of successive elastically coupled trinuclear (A=B=C) blocks, in which each site (A, B, and C) may occupy two electronic configurations, namely, low-spin (LS) and high-spin (HS) states, accompanied with structural changes.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK, LS2 9JT.
Inorg Chem
December 2024
LCC, CNRS and Université de Toulouse, UPS, INP, Toulouse 31077, France.
This study explores a Hofmann-type clathrate, {Fe(2,4-(OCH)-bpy)(HO)[μ-Pt(CN)][μ-Pt(CN)]·4HO}, which exhibits a thermally activated electron transfer (ET) without spin crossover. Synthesized as microcrystalline powders and single crystals, this compound reveals significant structural changes upon variation of the temperature, including alterations in the iron coordination sphere due to the large movement of the bipyridinium ligand. These changes correlate with a thermochromic hysteretic transition from yellow to orange.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
November 2024
Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387, Kraków, Poland.
The bistability of multiple physical properties driven by external stimuli in a solid is a desired prerequisite for its application in memory devices with convenient data readout. We present a pathway for thermal bistability detectable in four physical properties: magnetic, light absorption, second-harmonic generation (SHG), and dielectric. We report a novel heterometallic (TBA){[Fe(phIN)][Re(CN)]} ⋅ (phIN) (1) (TBA=tetrabutylammonium cation, phIN=phenyl isonicotinate) cyanido-bridged chain material.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
November 2024
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, P. R. China.
Dynamic molecules with tunable chemical and physical properties in response to external stimuli hold great potential for applications in various fields such as information storage, smart molecular machines, and biomimetics. Among them, supramolecular springs and spin-crossover (SCO) complexes can both undergo visible macroscopic changes under heat or light stimulation. In this study, we synthesized a unique trinuclear Fe(II)-SCO complex, [(R-L)Fe{Au(CN)}] (R 1), using a chiral chelating ligand decorated with rotatable benzyl rings.
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