Nanoporous carbon materials are a versatile source of carbons that would be useful in applications ranging from electronics to electrochemical energy storage. Here, we focus on nanoporous carbon materials prepared by direct carbonization of zeolitic imidazolate frameworks (ZIF-8) towards supercapacitor applications. Several types of nanoporous carbons have been prepared by varying the applied carbonization temperature. The symmetric devices assembled using nanoporous carbon electrodes were tested for their optimal performance in the electrolyte of sulfuric acid solution. We demonstrate the effects of various factors (e.g., surface area, nitrogen content, degree of graphitization, and relative percentage of micropores) on the performance.
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http://dx.doi.org/10.1039/c6cp05555a | DOI Listing |
ACS Nano
January 2025
Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea.
Light metal-based nanomaterials are widely used for energy storage due to their high energy density and surface-to-volume ratio. However, their high reactivity is paradoxically both the source of advantageous properties and a hurdle to the fabrication of stable nanostructures. Here, we demonstrate the formation of nanoporous Mg via chemical redox agent-driven dealloying, which ensures minimized surface passivation and results in fine nanostructures with <50 nm of interconnected metallic ligament despite the labile chemical properties of Mg.
View Article and Find Full Text PDFInt J Mol Sci
January 2025
Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China.
It is challenging to handle heavy-metal-rich plants that grow in contaminated soil. The role of heavy metals in biomass on the physicochemical structure and electrochemical properties of their derived carbon has not been considered in previous research. In this study, Cu-ion hybrid nanoporous carbon (CHNC) is prepared from Cu content-contaminated biomass through subcritical hydrocharization (HTC) coupling pyrolytic activation processes.
View Article and Find Full Text PDFACS Nano
January 2025
Songshan Lake Materials Laboratory (SLAB), Dongguan 523808, P. R. China.
Electrocatalytic CO reduction into high-value multicarbon products offers a sustainable approach to closing the anthropogenic carbon cycle and contributing to carbon neutrality, particularly when renewable electricity is used to power the reaction. However, the lack of efficient and durable electrocatalysts with high selectivity for multicarbons severely hinders the practical application of this promising technology. Herein, a nanoporous defective AuCu single-atom alloy (De-AuCu SAA) catalyst is developed through facile low-temperature thermal reduction in hydrogen and a subsequent dealloying process, which shows high selectivity toward ethylene (CH), with a Faradaic efficiency of 52% at the current density of 252 mA cm under a potential of -1.
View Article and Find Full Text PDFFood Chem
January 2025
School of Public Health, Hebei Key Laboratory of Occupational Health and Safety for Coal Industry, North China University of Science and Technology, Tangshan 063210, Hebei, China. Electronic address:
Effective and convenient QuEChERS of lipophilic pesticides with wide pK range from strongly pigment-rich food samples remains a great challenge. Here, a ZIF-67 derived magnetic nanoporous carbon (Co@MPC) was firstly proposed for modified QuEChERS of carbamate pesticides (pK 4.3-12.
View Article and Find Full Text PDFSmall
January 2025
Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan, 430074, China.
Hard carbon (HC) materials are suitable anodes for sodium-ion batteries (SIBs) but still suffer from insufficient initial Coulombic efficiency (ICE). Promoting sodium storage via the pore filling mechanism is an effective way to improve the ICE, and the key here is regulating the pore structures of HC. In this work, coal-derived HC is successfully engineered with abundant accessible closed nanopores by treating the coal precursors with a facile destructive oxidation strategy.
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