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Substrate scope for trimethyllysine hydroxylase catalysis. | LitMetric
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Substrate scope for trimethyllysine hydroxylase catalysis.

Abbas H K Al Temimi Bas J G E Pieters Y Vijayendar Reddy Paul B White Jasmin Mecinović

Chem Commun (Camb)

Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.

Published: October 2016

Trimethyllysine hydroxylase (TMLH) is a non-haem Fe(ii) and 2-oxoglutarate dependent oxygenase that catalyses the C-3 hydroxylation of an unactivated C-H bond in l-trimethyllysine in the first step of carnitine biosynthesis. The examination of trimethyllysine analogues as substrates for human TMLH reveals that the enzyme does hydroxylate substrates other than natural l-trimethyllysine.

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 Source
http://dx.doi.org/10.1039/c6cc07845aDOI Listing

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