Various potable water and soil samples have been analyzed for tri- and dialkyllead compounds using a sensitive speciation procedure based on diethyldithiocarbamate extraction, Grignard derivatization and gas chromatography-atomic absorption spectrometry. The species are generally present as ultra-trace contaminants, and their abundance is critically discussed. In addition, a degradation study of ionic alkyllead in ambient matrices is presented.
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http://dx.doi.org/10.1016/0048-9697(89)90387-2 | DOI Listing |
J Sep Sci
November 2007
School of Chemistry, University of the Witwatersrand, Johannesburg, South Africa.
Lead is known to be toxic, especially in its organic forms (organolead, OL). In the environment tetraalkyllead species are rapidly degraded by sunlight and atmospheric constituents like ozone or hydroxyl radicals. Such breakdown yields the soluble forms such as trialkyllead and dialkyllead and finally ionic lead species.
View Article and Find Full Text PDFAnal Chem
April 2000
Analytical Chemistry Division, Faculty of Sciences, University of Cordoba, Spain.
A simple and novel screening method for lead compounds in environmental waters is proposed. The analytes, in an acetic medium, are sorbed on a C60 fullerene column as diethyldithiocarbamate complexes and subsequently eluted with isobutyl methyl ketone (IBMK), the lead being determined by flame atomic absorption spectrometry. The screening method acts as filter and indicates whether the target analytes are present above or below the detection limit of the method (0.
View Article and Find Full Text PDFJ Chromatogr B Biomed Sci Appl
September 1998
Departmento Química Analítica, Universidad de La Rioja, Logroño, Spain.
One analytical procedure for the determination of ionic alkyllead in human urine has been studied. The system consists of the extraction of Me3Pb+, Et3Pb+ and Pb2+ at pH 9.0 with diethyldithiocarbamate to an organic phase.
View Article and Find Full Text PDFSci Total Environ
August 1989
Department of Chemistry, University of Antwerp (U.I.A.), Wilrijk, Belgium.
Various potable water and soil samples have been analyzed for tri- and dialkyllead compounds using a sensitive speciation procedure based on diethyldithiocarbamate extraction, Grignard derivatization and gas chromatography-atomic absorption spectrometry. The species are generally present as ultra-trace contaminants, and their abundance is critically discussed. In addition, a degradation study of ionic alkyllead in ambient matrices is presented.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!