AI Article Synopsis
- Researchers discovered that changing the copper salt used in reactions with α-diazocarbonyl compounds can significantly alter the outcome of the reaction.
- This method allows for the efficient production of two different types of compounds—(Z)-α-fluorovinylphosphonate and alkyl-SCF PO(OEt) derivatives—just by altering the copper counteranion.
- Mechanistic studies indicate that two distinct paths are involved in the formation of these products, helping to explain the different reactivities observed.
Article Abstract
Herein, we report a copper salt-controlled divergent reactivity toward α-diazocarbonyl compounds. By a simple change of the copper counteranion under identical reaction conditions, the reported method allowed an easy access to either (Z)-α-fluorovinylphosphonate or alkyl-SCF PO(OEt) derivatives in good yields. Mechanistic studies were performed and suggested two different pathways to explain the formation of these products.
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| http://dx.doi.org/10.1002/anie.201608294 | DOI Listing |
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