Liquid-like dynamics of a covalent 1,4-phenylene rotator have been unveiled in 1 with a brominated stator showing type-II halogen bonds. This singular rotation is favored by synergistic molecular changes in stacked molecules, according to VT solid state NMR, H T relaxometry and VT X-ray experiments of this highly crystalline compound.
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Dimensional confinement and superdiffusive rotational motion of uniaxial colloids in the presence of cylindrical obstacles.
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Out of Equilibrium Group, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016, India.
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Biochem Biophys Res Commun
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Graduate School of Chemical Sciences and Engineering, Hokkaido University, N13, W8, Sapporo, 060-8628, Japan; Department of Chemistry, Faculty of Science, Hokkaido University, N8, W5, Sapporo, 060-0810, Japan. Electronic address:
Bicelles, an artificial disk-shaped lipid bilayer, are commonly used for the structural and functional characterization of membrane-bound proteins in an environment similar to that in intracellular membranes. Because the dynamics of the lipids that constitute bicelles exert a significant impact on the structure and function of the inserted proteins, we investigated the mobility of lipid molecules in bicelles composed of DMPC (14:0 PC) and DHPC (06:0 PC) using solution NMR and MD calculations. C R relaxation experiments for the acyl groups demonstrated that increasing bicelle sizes limit the rotational diffusion of acyl chain H-C bonds in DMPC.
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ACS Nano
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Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China.
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