Two formamidinate bridged dirhodium(ii,ii) complexes with chelating diimine ligands L, [Rh(μ-DTolF)(L)], were shown to electrocatalytically reduce CO in the presence of HO. Analysis of the reaction mixture and headspace following bulk electrolysis revealed H and HCOOH as the major products. The variation in relative product formation is discussed.
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| http://dx.doi.org/10.1039/c6cc03253b | DOI Listing |
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