Two isostructural vanadium-based metal-organic polyhedra (denoted as VMOP-16 and VMOP-17) were synthesized by a solvothermal method, which are built from unprecedented {V} isopolyoxometalate clusters and dicarboxylate ligands. To our knowledge, the {V} second building unit is reported for the first time and features the highest nuclearity of vanadium-oxygen clusters compared with reported vanadium-based MOPs.
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http://dx.doi.org/10.1039/c6dt02764d | DOI Listing |
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