Visible-light-induced release of CO by thiolate iron(iii) carbonyl complexes bearing N,C,S-pincer ligands.

Dalton Trans

Division of Molecular Materials Science, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.

Published: October 2016

Iron(iii) carbonyl complexes are stabilized by a pincer ligand containing pyridine-N, phenyl-C and thiolate-S donors and two axial phosphine ligands. The N,C,S-pincer iron(iii) carbonyl complexes show CO-releasing properties induced by visible light.

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Source
http://dx.doi.org/10.1039/c6dt03399gDOI Listing

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