We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl{B-β-SiWO(OH)}] (1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by Tl NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.
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http://dx.doi.org/10.1021/acs.inorgchem.6b01921 | DOI Listing |
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