An Ultrastable Europium(III)-Organic Framework with the Capacity of Discriminating Fe/Fe Ions in Various Solutions.

Inorg Chem

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.

Published: October 2016

An ultrastable luminescent europium-organic framework, {[Eu(L)(HO)]·NMP·HO} (CTGU-2; NMP = N-methyl-2-pyrrolidone), can first detect Fe/Fe cations in different medium systems with high selectivity and sensitivity, and it also exhibits high sensitivity for CrO anion and acetone with a wide linear range and a low detection limit.

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http://dx.doi.org/10.1021/acs.inorgchem.6b01876DOI Listing

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