Over the past 15 years, sustainable chemistry has emerged as a new paradigm in the development of chemistry. In the field of organic synthesis, green chemistry rhymes with relevant choice of starting materials, atom economy, methodologies that minimize the number of chemical steps, appropriate use of benign solvents and reagents, efficient strategies for product isolation and purification and energy minimization. In that context, unconventional methods, and especially ultrasound, can be a fine addition towards achieving these green requirements. Undoubtedly, sonochemistry is considered as being one of the most promising green chemical methods (Cravotto et al. Catal Commun 63: 2-9, 2015). This review is devoted to the most striking results obtained in green organic sonochemistry between 2006 and 2016. Furthermore, among catalytic transformations, oxidation reactions are the most polluting reactions in the chemical industry; thus, we have focused a part of our review on the very promising catalytic activity of ultrasound for oxidative purposes.
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http://dx.doi.org/10.1007/s41061-016-0074-7 | DOI Listing |
J Org Chem
January 2025
Institute of Organic Chemistry, RWTH Aachen University, 52074 Aachen, Germany.
In contrast to what one can be led to believe upon inspecting some of the recent literature, the dehydrogenative phenothiazination reaction does not require onerous technologies, complicated setups, or advanced catalysts in order to be mild and sustainable. We demonstrate this herein with a most facile, cost-effective, and sustainable Cu(II) catalyzed method, under 1 atm of O at room temperature in methanol, providing broad scope and high yields. These new results further set the dehydrogenative phenothiazination reaction among the green and practical coupling concepts of chemistry.
View Article and Find Full Text PDFPharm Dev Technol
January 2025
Guangxi Key Laboratory of Special Biomedicine; School of Medicine, Guangxi University, Nanning, 530004, China.
Objective: This study aims to develop a dual-ligand-modified targeted drug delivery system by integrating photosensitizers and chemotherapeutic drugs to enhance anti-glioma effects. The system is designed to overcome the blood-brain barrier (BBB) that hinders effective drug delivery, increase drug accumulation in glioma cells, and thereby enhance therapeutic efficacy.
Methods: Liposomes were prepared using the film dispersion-ammonium sulfate gradient technique, co-loading the photosensitizer indocyanine green (ICG) and the chemotherapeutic drug mitoxantrone (MTO).
Int J Phytoremediation
January 2025
Institute of Soil & Environmental Sciences, University of Agriculture, Pakistan.
Due to a lack of high-quality water, farmers have been compelled to use sewage water for irrigation, contaminating agricultural soils with multiple heavy metals. For the remediation of contaminated soil, plant growth-promoting rhizobacteria (PGPR), pressmud (PM), and iron (III) oxide were used to improve the growth and phytostabilization potential of chickpea grown in contaminated soil. Contaminated soil was collected from a nearby field, receiving sewage and factory water over the last 60 years.
View Article and Find Full Text PDFFront Chem
December 2024
Department of Chemistry, University of Wyoming, Laramie, WY, United States.
Covalent integration of polymers and porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs), represent a promising strategy for overcoming the existing limitations of traditional porous materials. This integration allows for the combination of the advantages of polymers, i.e.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Biotechnology, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai 602105, Tamil Nadu, India.
The efficacy of the nanocomposite of manganese dioxide and diosgenin-incorporated chitosan (MnO/Dio@CS) was assessed by studying the photodegradation of two organic dyes, Acid Green (AG) and Malachite Green Oxalate (MGO), under visible light irradiation. The synthesized MnO/Dio@CS nanocomposites were characterized by Field Emission Scanning Electron Microscopy (FESEM), High-Resolution Transmission Electron Microscopy (HRTEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), UV-vis spectroscopy. The MnO/Dio@CS nanocomposites exhibited exceptional photocatalytic efficacy, prolonged durability, and quick degradation of the dye solution to 87.
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