A new type of neutron-scattering spectroscopy is presented that is designed specifically to measure dynamics in bio-systems that are difficult to obtain in any other way. The temporal information is largely model-free and is analogous to relaxation processes measured with dielectric spectroscopy, but provides additional spacial and geometric aspects of the underlying dynamics. Numerical simulations of the basic instrument design show the neutron beam can be highly focussed, giving efficiency gains that enable the use of small samples. Although we concentrate on continuous neutron sources, the extension to pulsed neutron sources is proposed, both requiring minimal data-treatment and being broadly analogous with dielectric spectroscopy, they will open the study of dynamics to new areas of biophysics.
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http://dx.doi.org/10.1038/srep34266 | DOI Listing |
Phys Chem Chem Phys
January 2025
Department of Chemical Engineering, National Institute of Technology, Nara College, Yamatokoriyama, Nara 639-1080, Japan.
This study focuses on two types of phosphonium cation-based ionic liquids (P-ILs) with different alkyl chains: triethylalkylphosphonium (P222R) and tributylalkylphosphonium (P444R) cations. Broadband dielectric spectroscopy showed that the translational motion of the ions accelerated with an increasing number of alkyl chains by coupling with their rotational motion in both P-ILs. Raman spectroscopy revealed that P222R cations, despite dielectric similarities to P444R cations, can form all-trans conformations and cation-rich nanodomains because they have a relatively polar, short alkyl chain moiety with a central P atom and less-polar alkyl chains than those of P444R cations.
View Article and Find Full Text PDFPLoS One
January 2025
Department of Physics, Bangladesh University of Engineering and Technology (BUET), Dhaka, Bangladesh.
High dielectric constants with less dielectric loss composites is highly demandable for technological advancements across various fields, including energy storage, sensing, and telecommunications. Their significance lies in their ability to enhance the performance and efficiency of a wide range of devices and systems. In this work, the dielectric performance of graphene oxide (GO) reinforced plasticized starch (PS) nanocomposites (PS/GO) for different concentrations of GO nanofiller was studied.
View Article and Find Full Text PDFSci Rep
January 2025
Wide Bandgap Semiconductor Technology Disciplines State Key Laboratory, Xidian University, Xi'an, 710071, China.
(AlO)(HfO) films with varying compositions were deposited on silicon substrates via plasma-enhanced atomic layer deposition (PEALD), and metal-oxide-semiconductor (MOS) capacitors were fabricated. The impact of varying induced Al content on the dielectric properties of HfO was examined through electrical measurements. The results showed that increasing Al content raised the flat-band voltage, reduced the interface state density (D), and significantly lowered the leakage current at a given voltage.
View Article and Find Full Text PDFNano Lett
January 2025
Institute for Experimental and Applied Physics, University of Regensburg, 93040 Regensburg, Germany.
Understanding and controlling the electronic properties of two-dimensional materials are crucial for their potential applications in nano- and optoelectronics. Monolayer transition metal dichalcogenides have garnered significant interest due to their strong light-matter interaction and extreme sensitivity of the band structure to the presence of photogenerated electron-hole pairs. In this study, we investigate the transient electronic structure of monolayer WS on a graphene substrate after resonant excitation of the A-exciton using time- and angle-resolved photoemission spectroscopy.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Laboratory of Polymer and Colors Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece.
The present work focuses on the synthesis and characterization of biobased lignin-poly(lactic) acid (PLA) composites. Organosolv lignin, extracted from beechwood, was used as a filler at 0.5, 1.
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