Characterization of Heterocoagulation with Oppositely Charged Polymer Colloid Particles through Online Tracking of Light Transmittance.

Heterocoagulation of colloid particles with opposite surface charge has been used for the preparation of composite microspheres with specifically designed suprastructure, such as those with raspberry-like surface morphology and core-shell microspheres, which are difficult to achieve through other techniques. Here we report our investigation on the heterocoagulation of cationic polystyrene (PS) particles with anionic poly(methyl methacrylate) (PMMA) particles by a novel technique, i.e., by following online the evolution of the light transmittance in the process with practically no disturbance of the dispersion and no post-treatment for the samples. Different heterocoagulations were conducted with PS and PMMA latexes with different latex mixing regimes and different particle sizes for both latexes. The evolution of the light transmittance in all of these processes, mainly with addition of anionic latex to cationic latex, was followed online. By combining TEM to detect the morphology of the composite microspheres formed and light scattering to follow the size evolution in the heterocoagulation, this work gives a clear picture of the heterocoagulation process. In addition, a set of mathematical equations are established in order to estimate the number ratio of the particles with opposite charge and the surface coverage percent of the large primary particle with the small ones. Results show that the particle size plays a key role in the process. The mechanism of the heterocoagulation process is discussed.