Organometallic halide perovskites solar cells are fabricated on nano-scaled corrugated substrates using a sequential deposition method. The corrugated substrates are fabricated using colloidal lithography followed by reactive ion etching. The corrugated structure is found to accelerate the chemical reaction between the sequentially deposited lead iodide (PbI ) and methyl ammonium iodide layers to form stoichiometric perovskite films, and the corrugated morphology is preserved at the interface of the hole transport layer (HTL) and the perovskite layer. The shunt resistance of the corrugated devices is found to be higher than that of the planar devices, leading to a higher open circuit voltage (V ) and fill factor (FF) in the corrugated devices. Finite-difference time-domain simulation is carried out on both planar and corrugated devices. The results revealed that light absorption is enhanced in the corrugated devices due to the corrugated HTL/perovskite interface, resulting in a significantly higher short circuit current (J ) observed in the corrugated devices. As a result, the average power conversion efficiency increases from 8.7% for the planar devices to 13% for the corrugated devices.
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http://dx.doi.org/10.1002/smll.201601974 | DOI Listing |
Int J Biol Macromol
January 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, PR China. Electronic address:
Multidirectional strain sensors are of technological importance for wearable devices and soft robots. Here, we report that flexible materials capable of multidirectional anisotropic strain sensing can be constructed leveraging diffusion-induced infiltration of monomers and in situ polymerization of metal ion-containing double network hydrogels in and on the surface of micro-corrugated chiral nematic cellulose nanocrystal/glucose films. Integrating the micro-corrugated cellulose nanocrystal/glucose chiral nematic films with ionic conductive hydrogels of PAA-co-AAm/sodium alginate/Al endows the materials with multidirectional mechanoelectrical resistivity and mechanochromism anisotropy.
View Article and Find Full Text PDFAnal Chem
January 2025
Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, United States.
This study describes a microfluidic thread-based analytical device (μTAD) capable of in situ mass spectrometric analysis for continuous flow reaction monitoring. Organic reaction screening is foundational to drug discovery. Microfluidic devices are of special interest here because they provide continuous reaction monitoring with advantages such as the use of smaller reagent volumes and short analysis times.
View Article and Find Full Text PDFChem Sci
October 2024
Department of Chemical Sciences and Centre for Advanced Functional Materials, Indian Institute of Science Education and Research (IISER) Kolkata Mohanpur 741246 Nadia West Bengal India
Understanding the interplay between the molecular structure and material properties of emerging p-type organic semiconductors marks a significant stride in the advancement of molecular electronics. Among the array of promising materials, mechanically flexible single crystals of π-conjugated molecules stand out due to their potential for cutting-edge applications in organic electronics. Notably, derivatives of pyrazinoquinoxaline (PQ) are recognized as versatile building blocks for constructing π-conjugated systems, showcasing good semiconductor performance in organic field-effect transistors (OFETs).
View Article and Find Full Text PDFSci Rep
October 2024
Electrical and Computer Engineering Department, Colorado State University, Fort Collins, CO, USA.
In the modern landscape of optical communication networks, ensuring robust security is increasingly critical, particularly for applications requiring seamless integration and minimal attack surfaces. Photonic Physical Unclonable Functions (PUFs) leverage the response from the photonic devices that are prone to inherent physical variations to generate unique and unpredictable signature identifiers which are then utilized by an authentication system for identification or encryption purposes. These photonic PUFs can be cohesively integrated into systems that use optical communication, whereas using electronic PUFs would introduce additional vulnerabilities due to the need for signal-domain conversions between optical and electronic signals.
View Article and Find Full Text PDFInt J Pharm
December 2024
Laboratório de Farmacologia Molecular, Instituto de Tecnologia em Fármacos (Farmanguinhos), Fundação Oswaldo Cruz, Rio de Janeiro, Brazil. Electronic address:
Resistant M. tuberculosis strains threaten pulmonary tuberculosis (P-TB) control since they limit drug options. Drug repositioning and new development strategies are urgently required to overcome resistance.
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