Non-catalytic and catalytic degradation of effluent dissolved organic matter under UVA-and UVC-irradiation tracked by advanced spectroscopic tools.

Non-catalytic and catalytic photodegradation of effluent dissolved organic matter (EfDOM) was examined under two different light sources (UVA and UVC). The degradation behavior was tracked by dissolved organic carbon (DOC), UV absorbance, and different fluorescent components. Catalytic UV irradiation resulted in much higher degradation rates than those without photocatalysts (TiO and ZnO) regardless of the tracking variables. For non-catalytic degradation, the highest removal rates of UV absorbance were found at wavelengths close to the irradiation of either UVC or UVA, while the photocatalytic degradation rates were consistently higher at longer wavelengths. The pseudo first-order rates of UV absorbance individually calculated at several representative wavelengths were very consistent with the sequential orders interpreted from two-dimensional correlation spectroscopy (2D-COS). Excitation emission matrix - parallel factor analysis (EEM-PARAFAC) identified one tryptophan-like (C1) and two humic-like (C2 and C3) components from EfDOM samples. Among those, C1 exhibited the lowest adsorption extent and the highest degradation rates for both photocatalysts, suggesting that the photocatalysis is mainly governed by hydroxyl radicals in aqueous solution. All observed degradation behaviors were well explained by the irradiation wavelengths, the extent of adsorption onto catalysts, and the presumed structure of the tracked component. Our study demonstrated that EEM-PARAFAC and 2D-COS could provide further insights into both non-catalytic and catalytic degradation of EfDOM upon UV-irradiation.