A novel laminate system comprising of sheets of paper bound together using cellulose nanofibrils (CNF) is manufactured and characterized. Bonding properties of CNF were first confirmed through a series of peeling tests. Composite laminates were manufactured from sheets of paper bonded together using CNF at two different consistencies, press times, and press temperatures. Mechanical properties of the laminates in tension and bending were characterized and the results were statistically analyzed. Elastic modulus and strength results met or exceeded those of a short glass fiber reinforced polypropylene and various natural fiber-filled polypropylene composites as well as some wood and paper based laminates. Stiffness properties, assuming perfect bonding within the laminates, were successfully estimated through a classical laminated plate theory (CLPT) with only 2-10% variation compared to experimental results. Laminates, together with CNF-peeled surfaces, were observed and qualitatively analyzed by SEM imaging. Physical properties, namely, water absorption and thickness swelling were measured. Swelling was controlled by the addition of a small percentage of a cross-linking additive.
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http://dx.doi.org/10.1021/acsami.6b07655 | DOI Listing |
ACS Nano
January 2025
College of Polymer Science and Engineering, Sichuan University, State Key Laboratory of Polymer Materials Engineering, Chengdu 610065 Sichuan, China.
Ionic skin can mimic human skin to sense both temperature and pressure simultaneously. However, a significant challenge remains in creating precise ionic skins resistant to external stimuli interference when subjected to pressure. In this study, we present an innovative approach to address this challenge by introducing a highly anisotropic nanofluidic ionic skin (ANIS) composed of carboxylated cellulose nanofibril (CNF)-reinforced poly(vinyl alcohol) (PVA) nanofibrillar network achieved through a straightforward one-step hot drawing method.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Chemistry, College of Sciences, Shiraz University, Shiraz, Iran. Electronic address:
Outstanding properties of nanocellulose provide opportunities for novel applications in various fields, particularly tissue engineering. Despite of numerous useful characteristics of nanocellulose, its production methods suffer from the lack of control of morphology, high cost, and the use of organic solvents. On the other hand, hydrophilicity of nanocellulose is a significant challenge for its dispersion as a reinforcement in hydrophobic polymers matrix.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
State Key Laboratory of Metastable Materials Science and Technology, Hebei Key Laboratory of Applied Chemistry, Hebei Key Laboratory of Nanobiotechnology, Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse, Yanshan University, Qinhuangdao 066004, China. Electronic address:
Preparation of ion-conductive hydrogels with excellent mechanics, good conductivity and adhesiveness is promising for flexible sensors, but remains a challenge. Here, we prepare a self-adhesive and ion-conductive hydrogel by introducing cellulose nanofibers (CNF) and ZnSO into a covalently-crosslinked poly (acrylamide-co-2-acrylamide-2-methyl propane sulfonic acid) (P(AM-co-AMPS)) network. Owing to the hydrogen bonding and metal coordination interactions among P(AM-co-AMPS) chains, CNF, and Zn, the resulting P(AM-co-AMPS)/CNF/ZnSO hydrogel exhibits high stretchability (1092 %), high toughness (244 kJ m), and skin-like elasticity (3.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Biotransformation and Organic Biocatalysis Research Group, Department of Exact Sciences, Santa Cruz State University, 45654-370 Ilhéus, Brazil. Electronic address:
This study explored the synergistic combination of silver nanoparticles (AgNPs), eucalyptus-derived nanofibrillated cellulose (NFC) and cassava starch to develop bionanocomposites with advanced properties suitable for sustainable and antifungal packaging applications. The influence of AgNPs synthesized through a green method using cocoa bean shell combined with varying concentrations of NFC were investigated. Morphological (scanning electron microscopy and atomic force microscopy), optical (L*, C*, °hue, and opacity), chemical (Fourier transform infrared spectroscopy), mechanical (puncture force, tensile strength, and Young's modulus), rheological (flow curve and frequency sweeps, strain, and stress), barrier, and hydrophilicity properties (water vapor permeability, solubility, wettability, and contact angle), as well as the antifungal effect against pathogens (Botrytis cinerea, Penicillium expansum, Colletotrichum musae, and Fusarium semitectum), were analyzed.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Physical Chemistry and Soft Matter, Wageningen University and Research, 6708 WE Wageningen, Netherlands. Electronic address:
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