AI Article Synopsis
- Researchers are working on improving artificial photosynthetic systems for producing hydrogen from water using earth-abundant materials.
- The study introduces four Fe bis(benzenedithiolate) complexes that effectively catalyze hydrogen production when combined with water-soluble CdSe quantum dots and ascorbic acid under visible light.
- The complexity of activity in these systems is influenced by the type of ligand used and the surface treatment of the quantum dots, highlighting important factors for optimizing hydrogen production technologies.
Article Abstract
The development of active, robust systems for light-driven hydrogen production from aqueous protons based on catalysts and light absorbers composed solely of earth abundant elements remains a challenge in the development of an artificial photosynthetic system for water splitting. Herein, we report the synthesis and characterization of four closely related Fe bis(benzenedithiolate) complexes that exhibit catalytic activity for hydrogen evolution when employed in systems with water-soluble CdSe QDs as photosensitizer and ascorbic acid as a sacrificial electron source under visible light irradiation (520 nm). The complex with the most electron-donating dithiolene ligand exhibits the highest activity, the overall order of activity correlating with the reduction potential of the formally Fe(III) dimeric dianions. Detailed studies of the effect of different capping agents and the extent of surface coverage of these capping agents on the CdSe QD surfaces reveal that they affect system activity and provide insight into the continued development of such systems containing QD light absorbers and molecular catalysts for H2 formation.
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| http://dx.doi.org/10.1021/jacs.6b05040 | DOI Listing |
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