Concentrations, properties, and health risk of PM in the Tianjin City subway system.

A campaign was conducted to assess and compare the personal exposure in L3 of Tianjin subway, focusing on PM levels, chemical compositions, morphology analysis, as well as the health risk of heavy metal in PM. The results indicated that the average concentration of the PM was 151.43 μg/m inside the train of the subway during rush hours. PM concentrations inside car under the ground are higher than those on the ground, and PM concentrations on the platform are higher than those inside car. Regarding metal concentrations, the highest element in PM samples was Fe; the level of which is 17.55 μg/m. OC is a major component of PM in Tianjin subway. Secondary organic carbon is the formation of gaseous organic pollutants in subway. SEM-EDX and TEM-EDX exhibit the presence of individual particle with a large metal content in the subway samples. For small Fe metal particles, iron oxide can be formed easily. With regard to their sources, Fe-containing particles are generated mainly from mechanical wear and friction processes at the rail-wheel-brake interfaces. The non-carcinogenic risk to metals Cr, Ni, Cu, Zn and Pb, and carcinogenic hazard of Cr and Ni were all below the acceptable level in L3 of Tianjin subway.