Phosphorus in the catchment of high sediment load river: A case of the Yellow River, China.

Surface sediment samples concurrently collected in the catchment of the Ningxia-Inner Mongolian reach of Yellow River (NIMYR) were analyzed to determine the phosphorus and correlated physiochemical properties of sediments. Samples were obtained from three main areas: the riverbed surface sediment (RSS), the floodplain surface sediment (FSS) and the desert surface sediment (DSS). The sequence of phosphorus-contamination level in this catchment, determined by a cumulative distribution function and multivariate statistical analysis, were FSS>RSS>DSS. Moreover, because of the impacts of anthropogenic activities, the sampling site with the highest and lowest phosphorus concentration (mgkg) of this catchment appeared in RSS (749.40) and DSS (200.10) respectively. In addition, this is the first study to present a qualification of the effect of the sediment's physicochemical properties on phosphorus by the multivariate regression tree analysis. Co-precipitation of phosphate with calcite [i], phosphate absorbed onto ferric hydroxides [ii] and grain-size effect [iii] were the three main mechanisms for phosphorus distribution in the sediment of NIMYR. The contributions of these three mechanisms to RSS and FSS were, respectively, [i]>[iii]>[ii] and [i]>[ii]>[iii]. The heaviest phosphorus-contaminated group of RSS was primarily controlled by [i], whereas the heaviest phosphorus-contaminated group of FSS was controlled by [i] and [ii], indicating that the FSS had a higher potential risk of releasing phosphorus from the sediment to overlying water.