The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centre.

Chem Commun (Camb)

Department of Organic Chemistry, University of Geneva, 30 quai Ernest Ansermet, 1211 Geneva, Switzerland.

Published: August 2016

We report herein the highly diastereoselective synthesis of octahedral cationic Ir(iii) hydride complexes with a stereogenic metal centre following various strategies. The configurational stability of these compounds has also been investigated.

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Source
http://dx.doi.org/10.1039/c6cc06020jDOI Listing

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