Conjugated assembly of colloidal zinc oxide quantum dots and multiwalled carbon nanotubes for an excellent photosensitive ultraviolet photodetector.

Conjugation of highly dense colloidal zinc oxide quantum dots (ZnO QDs) on multiwalled carbon nanotubes (ZnO QDs@MWCNTs) is achieved for high performance ultraviolet (UV) photodetection. Significant improvement in the photoresponse of the ZnO QDs@MWCNTs photodetector (PD) is established as compared to a pristine ZnO QDs PD. The conjugation of two constituents allows the direct transfer of photoinduced charge carriers in ZnO QDs to MWCNTs for an efficient electrical path that considerably reduces charge recombination during UV exposure. Linearity in the response current with both the UV illumination intensity as well as external bias voltage reveals the photoelastic behavior of the ZnO QDs@MWCNTs PD. Moreover, the PD displays faster response and recovery times of 1.6 s and 1.9 s, respectively, than the most conventional PDs. In addition, spectral photoresponse analysis of the PD presents visible-blind behavior. Overall, conjugation of the hybrid heterostructure presented excellent photoelastic, high performance and visible-blind UV photodetection.