AI Article Synopsis
- Mono(phosphine)-M complexes (M = Rh and Ir) were synthesized through postsynthetic metalation of a porous metal-organic framework (MOF) based on triarylphosphine.
- These complexes showed high efficiency in reactions such as hydrosilylation of ketones and alkenes, hydrogenation of alkenes, and C-H borylation of arenes.
- The MOF catalysts were recyclable and outperformed traditional homogeneous catalysts by stabilizing reactive intermediates and preventing unwanted reactions during the catalytic processes.
Article Abstract
Mono(phosphine)-M (M-PR3; M = Rh and Ir) complexes selectively prepared by postsynthetic metalation of a porous triarylphosphine-based metal-organic framework (MOF) exhibited excellent activity in the hydrosilylation of ketones and alkenes, the hydrogenation of alkenes, and the C-H borylation of arenes. The recyclable and reusable MOF catalysts significantly outperformed their homogeneous counterparts, presumably via stabilizing M-PR3 intermediates by preventing deleterious disproportionation reactions/ligand exchanges in the catalytic cycles.
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| http://dx.doi.org/10.1021/jacs.6b06239 | DOI Listing |
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