Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acsami.6b08439 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Redox potential tuning by calcium ions in a novel c-type cytochrome from an anammox organism.
J Biol Chem
December 2024
Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Jahnstrasse 29, D-69120 Heidelberg, Germany. Electronic address:
The electrochemical potentials of redox-active proteins need to be tuned accurately to the correct values for proper biological function. Here we describe a diheme cytochrome c with high heme redox potentials of about +350 mV, despite having a large overall negative charge which typically reduces redox potentials. High resolution crystal structures, spectroelectrochemical measurements and high-end computational methods show how this is achieved: each heme iron has a calcium cation positioned next to it at a distance of only 6.
View Article and Find Full Text PDFTwo-Dimensional Covalent Organic Frameworks: Structural Insights across Different Length Scales and Their Impact on Photocatalytic Efficiency.
Acc Chem Res
November 2024
Department of Chemistry, Functional Materials Technische Universität Berlin, 10623 Berlin, Germany.
ConspectusCovalent organic frameworks (COFs) are a rapidly emerging class of crystalline porous polymers, characterized by their highly defined, predictable, and tunable structure, porosity, and properties. COFs can form both two-dimensional (2D) and three-dimensional (3D) architectures, each with unique characteristics and potential applications. 2D COFs have attracted particular interest due to their favorable structural and optoelectronic properties.
View Article and Find Full Text PDFDesign of Cr-Based Molecular Electrocatalyst Systems for the CO Reduction Reaction.
Acc Chem Res
August 2024
Department of Chemistry, University of Virginia, PO Box 400319, Charlottesville, Virginia 22904-4319, United States.
ConspectusHuman influence on the climate system was recently summarized by the sixth Intergovernmental Panel on Climate Change (IPCC) Assessment Report, which noted that global surface temperatures have increased more rapidly in the last 50 years than in any other 50-year period in the last 2000 years. Elevated global surface temperatures have had detrimental impacts, including more frequent and intense extreme weather patterns like flooding, wildfires, and droughts. In order to limit greenhouse gas emissions, various climate change policies, like emissions trading schemes and carbon taxes, have been implemented in many countries.
View Article and Find Full Text PDFStrongly facet-dependent activity of iron-doped β-nickel oxyhydroxide for the oxygen evolution reaction.
Phys Chem Chem Phys
May 2024
Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544-5263, USA.
Iron (Fe)-doped β-nickel oxyhydroxide (β-NiOOH) is a highly active, noble-metal-free electrocatalyst for the oxygen evolution reaction (OER), with the latter being the bottleneck in electrochemical water splitting for sustainable hydrogen production. The mechanisms underlying how the Fe dopant modulates this host material's water electro-oxidation activity are still not entirely clear. Here, we combine hybrid density functional theory (DFT) and Hubbard-corrected DFT to investigate the OER activity of the most thermodynamically favorable (and therefore, expected to be the majority) crystallographic facets of β-NiOOH, namely (0001) and (101̄0).
View Article and Find Full Text PDFDevelopment of a multi-step screening procedure for redox active molecules in organic radical polymer anodes and as redox flow anolytes.
J Comput Chem
May 2024
Physikalisch-Chemisches Institut, Justus-Liebig-Universität Gießen, Gießen, Germany.
Benzo[d]-X-zolyl-pyridinyl (XO, S, NH) radicals represent a promising class of redox-active molecules for organic batteries. We present a multistep screening procedure to identify the most promising radical candidates. Experimental investigations and highly correlated wave function-based calculations are performed to determine benchmark redox potentials.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!