Polaritons are quasiparticles that form in semiconductors when an elementary excitation such as an exciton or a phonon interacts sufficiently strongly with light. In particular, exciton-polaritons have attracted tremendous attention for their unique properties, spanning from an ability to undergo ultra-efficient four-wave mixing to superfluidity in the condensed state. These quasiparticles possess strong intrinsic nonlinearities, while keeping most characteristics of the underlying photons. Here we review the most important features of exciton-polaritons in microcavities, with a particular emphasis on the emerging technological applications, the use of new materials for room-temperature operation, and the possibility of exploiting polaritons for quantum computation and simulation.
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http://dx.doi.org/10.1038/nmat4668 | DOI Listing |
Chem Commun (Camb)
January 2025
Research Institute for Electronic Science (RIES), Hokkaido University, N20W10, Kita ward, Hokkaido 001-0020, Japan.
Photochemical reactions enable the synthesis of energetically unfavorable compounds but often require irradiation with ultraviolet light, which potentially induces side reactions. Here, cavity strong coupling enhances the efficiency of an all-solid state photocyclization in crystals of 2,4-dimethoxy-β-nitrostyrene under irradiation with visible light. The exposure to visible light facilitates photocyclization by the transition to a lower polaritonic state, which is energetically lower than the original transition state.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
School of Precision Instruments and Opto-Electronics Engineering, Tianjin University, Tianjin, 300072, China.
Terahertz (THz) polarization detection facilitates the capture of multidimensional data, including intensity, phase, and polarization state, with broad applicability in high-resolution imaging, communication, and remote sensing. However, conventional semiconductor materials are limited by energy band limitations, rendering them unsuitable for THz detection. Overcoming this challenge, the realization of high-stability, room-temperature polarization-sensitive THz photodetectors (PDs) leveraging the thermoelectric effect of Cs(FAMA)Pb(IBr) (CsFAMA)/metasurfaces is presented.
View Article and Find Full Text PDFNanophotonics
June 2024
Department of Chemistry, University of Rochester, 120 Trustee Road, Rochester, NY 14627, USA.
We present a theory that explains the resonance effect of the vibrational strong coupling (VSC) modified reaction rate constant at the normal incidence of a Fabry-Pérot (FP) cavity. This analytic theory is based on a mechanistic hypothesis that cavity modes promote the transition from the ground state to the vibrational excited state of the reactant, which is the rate-limiting step of the reaction. This mechanism for a single molecule coupled to a single-mode cavity has been confirmed by numerically exact simulations in our recent work in [J.
View Article and Find Full Text PDFNano Lett
December 2024
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, 199 Ren'ai Road, Suzhou 215123, Jiangsu, P. R. China.
Strong coupling between excitons and photons in optical microcavities leads to the formation of exciton polaritons, which maintain both the coherence of light and the interaction of matter. Recently, atomically thin monolayer semiconductors with a large exciton oscillator strength and high exciton binding energy have been widely used for realizing room-temperature exciton polaritons. Here, we demonstrated room-temperature exciton polaritons with a monolayer molecular crystal.
View Article and Find Full Text PDFChempluschem
October 2024
Department of Chemical Sciences, Tata Institute of Fundamental Research (TIFR), Homi Bhabha Road, Mumbai, 400005, India.
Light-matter strong coupling, especially Vibrational Strong Coupling (VSC), has become a significant research focus due to its potential to alter materials' inherent physical and chemical properties. Remarkably, VSC operates even in the absence of light, harnessing subtle quantum fluctuations to influence material characteristics. Vibro-polaritonic states, which are half photonic and half material, are introduced in the molecular/material energy ladder under VSC conditions.
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