Fluorinated polyurethanes with a glass transition temperature as low as -139 °C and a decomposition onset temperature of 247-330 °C were prepared by a reaction of fluorinated alcohols with aromatic and cycloaliphatic diisocyanates in solution or melt.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273135PMC
http://dx.doi.org/10.3390/molecules21070904DOI Listing

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