Supercapacitive microbial fuel cells with various anode and cathode dimensions were investigated in order to determine the effect on cell capacitance and delivered power quality. The cathode size was shown to be the limiting component of the system in contrast to anode size. By doubling the cathode area, the peak power output was improved by roughly 120% for a 10ms pulse discharge and internal resistance of the cell was decreased by ∼47%. A model was constructed in order to predict the performance of a hypothetical cylindrical MFC design with larger relative cathode size. It was found that a small device based on conventional materials with a volume of approximately 21cm(3) would be capable of delivering a peak power output of approximately 25mW at 70mA, corresponding to ∼1300Wm(-3).
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http://dx.doi.org/10.1016/j.biortech.2016.06.105 | DOI Listing |
Curr Opin Biotechnol
February 2022
Department of Analytical Chemistry/Biochemistry and Structural Biology, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden. Electronic address:
Supercapacitive biofuel cells' (SBFCs) most recent advancements are herein disclosed. In conventional SBFCs the biocomponent is employed as the pseudocapacitive component, while in self-charging biodevices it also works as the biocatalyst. The performance of different types of SBFCs are summarized according to the categorization based on the biocatalyst employed: supercapacitive microbial fuel cells (s-MFCs), supercapacitive biophotovoltaics (SBPV) and supercapacitive enzymatic fuel cells (s-EFCs).
View Article and Find Full Text PDFInt J Hydrogen Energy
September 2020
Bristol BioEnergy Centre, Bristol Robotics Laboratory, UWE, T-Block Coldharbour Lane, Bristol, BS16 1QY, UK.
Self-stratifying microbial fuel cells with three different electrodes sizes and volumes were operated in supercapacitive mode. As the electrodes size increased, the equivalent series resistance decreased, and the overall power was enhanced (small: ESR = 7.2 Ω and P = 13 mW; large: ESR = 4.
View Article and Find Full Text PDFElectrochim Acta
September 2020
Bristol BioEnergy Centre, Bristol Robotics Laboratory, T-Block, UWE, Coldharbour Lane, Bristol BS16 1QY, UK.
In this work, a membraneless microbial fuel cell (MFC) with an empty volume of 1.5 mL, fed continuously with hydrolysed urine, was tested in supercapacitive mode (SC-MFC). In order to enhance the power output, a double strategy was used: i) a double cathode was added leading to a decrease in the equivalent series resistance (ESR); ii) the apparent capacitance was boosted up by adding capacitive features on the anode electrode.
View Article and Find Full Text PDFBioresour Technol Rep
September 2019
Bristol BioEnergy Centre, Bristol Robotics Laboratory, T-Block, UWE, Coldharbour Lane, Bristol BS16 1QY, UK.
Microbial fuel cells (MFCs) with paper separators and liquid containing elements were investigated in supercapacitive mode. MFCs (15 mL) in a supercapacitive configuration, consisted of plain wrapped carbon veil anode (negative) and conductive latex cathode (positive). The internal supercapacitor is discharged galvanostatically and is self-recharged as red-ox reactions occur on both electrodes.
View Article and Find Full Text PDFBiosens Bioelectron
September 2019
Bioelectronics & Microsystems Laboratory, Department of Electrical & Computer Engineering, State University of New York-Binghamton, Binghamton, NY 13902, USA. Electronic address:
Microliter-scale photosynthetic microbial fuel cells (micro-PMFC) can be the most suitable power source for unattended environmental sensors because the technique can continuously generate electricity from microbial photosynthesis and respiration through day-night cycles, offering a clean and renewable power source with self-sustaining potential. However, the promise of this technology has not been translated into practical applications because of its relatively low performance. By creating an innovative supercapacitive micro-PMFC device with maximized bacterial photoelectrochemical activities in a well-controlled, tightly enclosed micro-chamber, this work established innovative strategies to revolutionize micro-PMFC performance to attain stable high power and current density (38 μW/cm and 120 μA/cm) that then potentially provides a practical and sustainable power supply for the environmental sensing applications.
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