Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273782 | PMC |
http://dx.doi.org/10.3390/molecules21070878 | DOI Listing |
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