A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a Au(I) -catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5132091 | PMC |
http://dx.doi.org/10.1002/anie.201604952 | DOI Listing |
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